NOVEL ALKYLATION ANNULATION REACTION OF FISCHER CARBENE COMPLEXES

被引：11

作者：

AMIN, SR

SAWANT, SS

PURANIK, VG

SARKAR, A

机构：

[1] NATL CHEM LAB,DIV ORGAN CHEM SYNTH,POONA 411008,MAHARASHTRA,INDIA

[2] NATL CHEM LAB,DIV PHYS CHEM,POONA 411008,MAHARASHTRA,INDIA

来源：

ORGANOMETALLICS | 1995年 / 14卷 / 08期

关键词：

D O I：

10.1021/om00008a004

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Alkylation of aminocarbene complexes (CO)(5)M=C(CH3)(NHR) with dichloromethane or dibromomethane under PTC conditions triggers an annulation. reaction, leading to novel cyclic products. This is the first example of such reactivity of Fischer carbene complexes.

引用

页码：3617 / 3619

页数：3

共 41 条

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