PHASE-EQUILIBRIA IN THE LIQUID SULFUR TELLURIUM SYSTEM - STRUCTURAL-CHANGES AND 2-MELT PHASE-SEPARATION

被引：21

作者：

TSUCHIYA, Y

机构：

[1] Dept. of Phys., Fac. of Sci., Niigata Univ.

来源：

JOURNAL OF PHYSICS-CONDENSED MATTER | 1992年 / 4卷 / 18期

关键词：

D O I：

10.1088/0953-8984/4/18/002

中图分类号：

O469 [凝聚态物理学];

学科分类号：

070205 ;

摘要：

A two-melt region bounded by a closed loop in the composition-temperature plane has been found in the liquid S-Te system, which is the first example for a liquid having electrical conductivity. It is located in an extremely narrow range centred at about 39.2 at. % S and 715-degrees-C near the threshold of the non-metal-metal transition. It has been shown that structural change in the liquid causes the two-melt phase separation.

引用

页码：4335 / 4349

页数：15

共 23 条

[1]

CULTER M, 1985, LOCALIZATION METAL I, P119

[2] ELECTROSTRICTION IN THE SEMICONDUCTOR-TO-METAL TRANSITION OF LIQUID SE-TE ALLOYS [J].

CUTLER, M ;

KAO, SS ;

SILVA, LA .

PHYSICAL REVIEW B, 1990, 41 (06) :3339-3347

[3]

HANSEN M, 1958, CONSTITUTION BINARY, P1165

[4] HEAT-CAPACITY OF LIQUID SE-TE MIXTURES [J].

KAKINUMA, F ;

OHNO, S .

JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 1987, 56 (02) :619-628

[5] ELECTRONIC-PROPERTIES OF LIQUID S-TE MIXTURES [J].

KAKINUMA, F ;

OKADA, T ;

OHNO, S .

JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 1986, 55 (01) :284-294

[6] SPECIFIC-HEAT OF LIQUID TE-BASED MIXTURES [J].

KAKINUMA, F ;

OHNO, S .

ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE NEUE FOLGE, 1988, 156 :265-269

[7] The determintation of the molecular complexity of liquid sulphur [J].

Kellas, AM .

JOURNAL OF THE CHEMICAL SOCIETY, 1918, 113 :903-922

[8] ENTHALPIES OF BINARY-MIXTURES OF CHALCOGEN ELEMENTS [J].

MAEKAWA, T ;

YOKOKAWA, T ;

NIWA, K .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1973, 46 (03) :761-765

[9]

MENNELE A, 1988, EUROPHYS LETT, V4, P707

[10]

MENNELLE A, 1989, PHYSICA B, V156, P174

← 1 2 3 →