A VERY USEFUL AND EFFICIENT WACKER OXIDATION OF HIGHER ALPHA-OLEFINS IN THE PRESENCE OF PER(2,6-DI-O-METHYL)-BETA-CYCLODEXTRIN

被引：35

作者：

MONFLIER, E

TILLOY, S

FREMY, G

BARBAUX, Y

MORTREUX, A

机构：

[1] Laboratoire de Catalyse Homogène, Hétérogène associé au CNRS, ENSCL Bâtiment C7, 59659 Villeneuve d'Ascq

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 03期

关键词：

WACKER OXIDATION; HIGHER ALPHA-OLEFIN; PER(2,6-DI-O-METHYL)-BETA-CYCLODEXTRIN;

D O I：

10.1016/0040-4039(94)02263-B

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Oxidation of higher alpha-olefins (C-8-C-16) in a two phase system with a multicomponent catalytic system, ie. PdSO4 / H9PV6Mo6O40 / CuSO4 and per(2,6-di-o-methyl)-beta-cyclodextrin gives the corresponding 2-ketones in high yields (> 90 %).

引用

页码：387 / 388

页数：2

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