SUPPRESSION OF ALKENE ISOMERIZATION IN PRODUCTS FROM INTRAMOLECULAR HECK REACTIONS BY ADDITION OF TL(I) SALTS

被引：134

作者：

GRIGG, R

LOGANATHAN, V

SANTHAKUMAR, V

SRIDHARAN, V

TEASDALE, A

机构：

[1] Chemistry Department, Leeds University, Leeds

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 05期

关键词：

D O I：

10.1016/S0040-4039(00)74860-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Palladium catalysed cyclisations creating products possessing spiro-, fused- and bridged-rings, and tetrasubstituted carbon centres as mixtures of double bond isomers are modified to give single products in the presence of Tl(1) salts.

引用

页码：687 / 690

页数：4

共 15 条

[1] PALLADIUM-CATALYZED POLYENE CYCLIZATIONS OF DIENYL ARYL IODIDES [J].

ABELMAN, MM ;

OVERMAN, LE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (07) :2328-2329

[2] THE SYNTHESIS OF FUSED RING NITROGEN-HETEROCYCLES VIA REGIOSPECIFIC INTRAMOLECULAR HECK REACTIONS [J].

GRIGG, R ;

SRIDHARAN, V ;

STEVENSON, P ;

SUKIRTHALINGAM, S ;

WORAKUN, T .

TETRAHEDRON, 1990, 46 (11) :4003-4018

[3] THE EFFECT OF THALLIUM (I) SALTS ON PALLADIUM CATALYZED TANDEM CYCLIZATION-ANION CAPTURE PROCESSES [J].

GRIGG, R ;

LOGANATHAN, V ;

SUKIRTHALINGAM, S ;

SRIDHARAN, V .

TETRAHEDRON LETTERS, 1990, 31 (45) :6573-6576

[4] PALLADIUM-CATALYZED POLYCYCLISATION-ANION CAPTURE PROCESSES [J].

GRIGG, R ;

DORRITY, MJ ;

MALONE, JF ;

SRIDHARAN, V ;

SUKIRTHALINGAM, S .

TETRAHEDRON LETTERS, 1990, 31 (09) :1343-1346

[5] THE SYNTHESIS OF SPIROCYCLIC COMPOUNDS BY REGIOSPECIFIC PALLADIUM CATALYZED CYCLIZATION REACTIONS [J].

GRIGG, R ;

SRIDHARAN, V ;

STEVENSON, P ;

SUKIRTHALINGAM, S .

TETRAHEDRON, 1989, 45 (11) :3557-3568

[6] TRANS 2,6-BIS[(DIMETHYLAMINO)METHYL]PHENYL-N,N',C COMPLEXES OF PD(II) AND PT(II) - CRYSTAL-STRUCTURE OF [PTI(MEC6H3(CH2NME2)2-O,O')]BF4 - A CYCLOHEXADIENYL CARBONIUM-ION WITH A SIGMA-BONDED METAL SUBSTITUENT [J].

GROVE, DM ;

VANKOTEN, G ;

LOUWEN, JN ;

NOLTES, JG ;

SPEK, AL ;

UBBELS, HJC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (24) :6609-6616

[7] MECHANISM OF ARYLATION AND CARBOMETHOXYLATION OF OLEFINS WITH ORGANOPALLADIUM COMPOUNDS [J].

HECK, RF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1969, 91 (24) :6707-&

[8] THE EFFECT OF ADDED SILVER-NITRATE ON THE PALLADIUM-CATALYZED ARYLATION OF ALLYLTRIMETHYLSILANES [J].

KARABELAS, K ;

WESTERLUND, C ;

HALLBERG, A .

JOURNAL OF ORGANIC CHEMISTRY, 1985, 50 (20) :3896-3900

[9] SYNTHESIS OF (E)-(2-ARYLETHENYL)SILANES BY PALLADIUM-CATALYZED ARYLATION OF VINYLSILANES IN THE PRESENCE OF SILVER-NITRATE [J].

KARABELAS, K ;

HALLBERG, A .

JOURNAL OF ORGANIC CHEMISTRY, 1986, 51 (26) :5286-5290

[10] STEREOSELECTIVE PALLADIUM-CATALYZED SYNTHESIS OF (Z)-TRIMETHYL(2-ARYLETHENYL)SILANES BY ARYLATION OF (E)-1,2-BIS(TRIMETHYLSILYL)ETHYLENE - EFFECTS OF ADDED HALIDES COMPARED TO SILVER SALTS [J].

KARABELAS, K ;

HALLBERG, A .

JOURNAL OF ORGANIC CHEMISTRY, 1989, 54 (07) :1773-1776

← 1 2 →