SUCROCHEMISTRY .35. THE USE OF PIVALIC ESTERS OF SUCROSE FOR THE SYNTHESIS OF CHLORO, AZIDO, AND ANHYDRO DERIVATIVES

被引：11

作者：

CHOWDHARY, MS ^{[1
]}

HOUGH, L ^{[1
]}

RICHARDSON, AC ^{[1
]}

机构：

[1] KINGS COLL LONDON, DEPT CHEM, KENSINGTON CAMPUS, CAMPDEN HILL RD, LONDON W8 7AH, ENGLAND

来源：

CARBOHYDRATE RESEARCH | 1986年 / 147卷 / 01期

关键词：

D O I：

10.1016/0008-6215(86)85006-6

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

2,3,6,1'',2'',3'',6''-Hepta-O-pivaloylsucrose, readily available from sucrose, has been converted into 4-chloro-4-deoxygalactosucroses, 4-amino-4-deoxygalactosucrose, and 4-deoxysucrose, via nucleophilic displacement reactions. Similarly, 3,6,1'',3'',4'',6''-hexa-O-pivaloysucrose and other readily available hexa-, penta and tri-pivalates have been converted into chloro and azido derivatives and also into various epoxides.

引用

页码：49 / 58

页数：10

共 7 条

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