PREPARATION AND STRUCTURE OF (BU(T)NTENPPH(2)NSIME(3))(2), A TELLURIUM DIIMIDE DIMER

被引：25

作者：

CHIVERS, T

GAO, XL

PARVEZ, M

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 18期

关键词：

D O I：

10.1039/c39940002149

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of Ph(2)P(NsiMe(3))(2)Te(Cl)=NR (R = PPh(2)NSiMe(3)) with Bu(t)NHLi in toluene at -78 degrees C produces the tellurium. diimide dimer (Bu(t)NTeNR)(2), which is shown by X-ray crystallography to consist of a planar four-membered Te2N2 ring with short exocyclic tellurium-nitrogen bonds.

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页码：2149 / 2150

页数：2

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