SYNTHESIS OF COORDINATIVELY UNSATURATED DIPHOSPHINE NICKEL(II) AND PALLADIUM(II) BETA-AGOSTIC ETHYL CATIONS - X-RAY CRYSTAL-STRUCTURE OF [NI(BUT2P(CH2)2PBUT2)(C2H5)][BF4]

被引：73

作者：

CONROYLEWIS, FM ^{[1
]}

MOLE, L ^{[1
]}

REDHOUSE, AD ^{[1
]}

LITSTER, SA ^{[1
]}

SPENCER, JL ^{[1
]}

机构：

[1] UNIV SALFORD, DEPT CHEM & APPL CHEM, SALFORD M5 4WT, LANCS, ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 22期

关键词：

D O I：

10.1039/c39910001601

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Protonation of [M(L2)(eta-2-C2H4)] (L2 = chelating diphosphine; M = Ni, Pd) with HBF4 affords a series of cations [M(L2)(C2H5)]+ characterized as beta-agostic ethyl complexes by NMR spectroscopy and X-ray structure analysis.

引用

页码：1601 / 1603

页数：3

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