SYNTHESIS OF BETA-HEMATIN BY DEHYDROHALOGENATION OF HEMIN

被引：60

作者：

BOHLE, DS

HELMS, JB

机构：

[1] Department of Chemistry, University of Wyoming, Laramie

来源：

BIOCHEMICAL AND BIOPHYSICAL RESEARCH COMMUNICATIONS | 1993年 / 193卷 / 02期

关键词：

D O I：

10.1006/bbrc.1993.1652

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

β-Hematin, the metalloporphyrin coordination polymer present in malaria pigment, is prepared in high yield by the abstraction of HCl from hemin with a non-coordinating base in strictly anhydrous conditions. The product of this preparation is characterized by elemental analysis, infrared and diffuse reflectance spectroscopies and demonstrated to be identical to prior preparations. © 1993 Academic press, Inc.

引用

页码：504 / 508

页数：5

共 18 条

[1] PROTON MAGNETIC RESONANCE SPECTRA OF PORPHYRINS .4. COPROPORPHYRIN TETRAMETHYL ESTERS
ABRAHAM, RJ
BURBIDGE, PA
JACKSON, AH
MACDONAL.DB
[J]. JOURNAL OF THE CHEMICAL SOCIETY B-PHYSICAL ORGANIC, 1966, (07): : 620 - &
[2] THE MALARIA PARASITE MONITORED BY PHOTOACOUSTIC-SPECTROSCOPY
BALASUBRAMANIAN, D
RAO, CM
PANIJPAN, B
[J]. SCIENCE, 1984, 223 (4638) : 828 - 830
[3] ULTRACENTRIFUGATION STUDIES ON AGGREGATION OF FERRIPROTOPORPHYRIN 9 BY ELECTROLYTES IN AQUEOUS ALKALINE MEDIUM
BLAUER, G
ZVILICHOVSKY, B
[J]. ARCHIVES OF BIOCHEMISTRY AND BIOPHYSICS, 1968, 127 (1-3) : 749 - +
[4] INFRARED EVIDENCE FOR AN OXO-BRIDGED (FE-O-FE) HAEMIN DIMER
BROWN, SB
JONES, P
LANTZKE, IR
[J]. NATURE, 1969, 223 (5209) : 960 - &
[5] AGGREGATION OF FERRIHAEMS - DIMERIZATION AND PROTOLYTIC EQUILIBRIA OF PROTOFERRIHAEM AND DEUTEROFERRIHAEM IN AQUEOUS SOLUTION
BROWN, SB
DEAN, TC
JONES, P
[J]. BIOCHEMICAL JOURNAL, 1970, 117 (04) : 733 - &
[6] DIMERIC NATURE OF HEMIN HYDROXIDES
COHEN, IA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1969, 91 (08) : 1980 - &
[7] THERMODYNAMIC AND KINETIC PROPERTIES OF AN IRON-PORPHYRIN SYSTEM
FLEISCHER, EB
PALMER, JM
SRIVASTAVA, TS
CHATTERJEE, A
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1971, 93 (13) : 3162 - +
[8] LEMBERG R, 1949, HEMATIN COMPOUNDS BI, P169
[9] AGGREGATION IN 5-COORDINATE HIGH-SPIN NATURAL HEMINS - DETERMINATION OF SOLUTION STRUCTURE BY H-1-NMR
MAZUMDAR, S
MITRA, S
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1990, 94 (02) : 561 - 566
[10] MICROSPECTROPHOTOMETRIC ANALYSIS OF MALARIAL PIGMENT
MORSELT, AFW
GLASTRA, A
JAMES, J
[J]. EXPERIMENTAL PARASITOLOGY, 1973, 33 (01) : 17 - 22

← 1 2 →