POLYMERIZABLE DERIVATIVES OF TRIPHENYLPHOSPHINE - ACYLATION OF TRIARYLPHOSPHINES BEARING ALCOHOL OR AMINE SUBSTITUENTS WITH ACRYLOYLCHLORIDE AND METHACRYLOYLCHLORIDE

被引：14

作者：

NIKITIDIS, A

ANDERSSON, C

机构：

[1] Inorganic Chemistry 1, Chemical Center, S 221 00 Lund

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1993年 / 78卷 / 1-4期

基金：

瑞典研究理事会;

关键词：

PHOSPHINE; MONOMER; ACYLATION; ACRYLOYLCHLORIDE; METHACRYLOYLCHLORIDE POLYMER-BOUND;

D O I：

10.1080/10426509308032430

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Methods to prepare amino substituted triaryl-phosphines viz. N-methyl-2-(diphenylphoshino)benzylamine, N-t-butyl-2-(diphenylphosphino)benzylamine and alpha,N-dimethyl-4-(diphenylphosphino)benzylamine are presented. The acylation of amino and alcohol substituted triarylphosphines have been studied and the amides N-methacryloyl-N-methyl-2-(diphenylphophino)benzylamine, N-methacryloyl-2-(diphenyl-phosphino)aniline, N-methacryloyl-N-methyl-4-(diphenylphosphino)benzylamine. N-methyl-N-propionyl-4-(diphenylphosphino)benzylamine, N-methyl-N-propionyl-2-(diphenylphosphino)benzylamine and N-acryloyl-N-methyl-4-(diphenylphosphino)benzylamine and the ester 2-(diphenylphosphino)benzyl methacrylate have been prepared.

引用

页码：141 / 152

页数：12

共 49 条

[1] ASYMMETRIC REACTIONS CATALYZED BY CHIRAL METAL-COMPLEXES .14. CATALYTIC ASYMMETRIC HYDROGENATIONS WITH POLYMER SUPPORTED CHIRAL PYRROLIDINEPHOSPHINE-RHODIUM COMPLEXES [J].