STEREOELECTRONICALLY CONTROLLED [2,3]WITTIG REARRANGEMENT OF ISOPROPYL 2'-HETEROSUBSTITUTED-2'-ALKENYLOXYACETATES

被引：5

作者：

ISHIKAWA, A ^{[1
]}

UCHIYAMA, H ^{[1
]}

KATSUKI, T ^{[1
]}

YAMAGUCHI, M ^{[1
]}

机构：

[1] KYUSHU UNIV 33,FAC SCI,DEPT CHEM,HIGASHI KU,FUKUOKA 812,JAPAN

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 17期

关键词：

D O I：

10.1016/S0040-4039(00)97376-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[2,3]Wittig rearrangement of 2′-heterosubstituted alkenyloxyacetic acid esters exhibited anti,Z-selectivity, which can be attributed to the interaction between the nonbonding orbital on the ether oxygen atom and the anti-bonding orbital of carbonheteroatom bond. © 1990.

引用

页码：2415 / 2418

页数：4

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