SISI COUPLING-CONSTANTS OF SYMMETRICAL DISILANES

被引：14

作者：

HASSLER, K ^{[1
]}

HENGGE, E ^{[1
]}

SCHRANK, F ^{[1
]}

WEIDENBRUCH, M ^{[1
]}

机构：

[1] UNIV OLDENBURG,FACHBEREICH CHEM,W-2900 OLDENBURG,GERMANY

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 1991年 / 47卷 / 01期

关键词：

D O I：

10.1016/0584-8539(91)80178-L

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

Si-29-Si-29-one bond coupling constants for a series of symmetric disilanes XH2SiSiH2X, X = Ph, I, Tf (Tf = OSO2CF3) and X2HSiSiHX2, X = Ph, I, Br, Me, tBu and Tf have been measured using a modified INADEQUATE pulse sequence. Correlations between SiSi coupling constants, force constants and SiH coupling constants are discussed.

引用

页码：57 / 62

页数：6

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