PHYSICAL AND MECHANICAL-PROPERTIES AND ENTHALPY RELAXATION BEHAVIOR OF POLYPHENYLENESULFIDESULFONE (PPSS)

被引：13

作者：

TAMADA, H ^{[1
]}

OKITA, S ^{[1
]}

KOBAYASHI, K ^{[1
]}

机构：

[1] TORAY INDUSTRIES LTD,PLAST RES LABS,9-1 OE CHO,MINATO KU,NAGOYA 455,JAPAN

来源：

POLYMER JOURNAL | 1993年 / 25卷 / 04期

关键词：

POLYPHENYLENESULFIDESULFONE; POLYETHERSULFONE; POLYSULFONE; ENTHALPY RELAXATION; BETA-RELAXATION;

D O I：

10.1295/polymj.25.339

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Physical and mechanical properties of polyphenylenesulfidesulfone (PPSS) were measured and compared with those of other high performance sulfur containing amorphous polymers such as polyethersulfone (PES) and polysulfone (PSF). PPSS showed poorer toughness than PES and PSF, and the enthalpy relaxation behavior of PPSS was investigated using DSC in order to understand the brittle nature of PPSS. The rate of enthalpy relaxation of PPSS was found to be very high and the fast relaxation is probably responsible for the brittle nature of PPSS. Dynamic mechanical spectra of PPSS were also measured to supplement the understanding of the relaxation behavior.

引用

页码：339 / 346

页数：8

共 16 条

[1]

ATTOWOOD TE, 1977, POLYMER, V18, P359

[2] POLY(ARYLENE ETHER SULFONES) BY POLYETHERIFICATION .1. SYNTHESIS OF HALOGENOPHENOLS [J].

ATTWOOD, TE ;

BARR, DA ;

FEASEY, GG ;

LESLIE, VJ ;

NEWTON, AB ;

ROSE, JB .

POLYMER, 1977, 18 (04) :354-358

[3]

DUUS F, 1979, COMPREHENSIVE ORGANI, V3, P374

[4] MECHANISM OF POLY(PARA-PHENYLENE SULFIDE) GROWTH FROM PARA-DICHLOROBENZENE AND SODIUM SULFIDE [J].

FAHEY, DR ;

ASH, CE .

MACROMOLECULES, 1991, 24 (15) :4242-4249

[5] SECONDARY RELAXATION PROCESSES IN BISPHENOL-A POLYSULFONE [J].

FRIED, JR ;

LETTON, A ;

WELSH, WJ .

POLYMER, 1990, 31 (06) :1032-1037

[6] ENTHALPY RELAXATION OF POLYETHERS HAVING PHENYLENE GROUPS IN THE MAIN CHAIN [J].

HATAKEYAMA, T ;

YOSHIDA, H ;

HIROSE, S ;

HATAKEYAMA, H .

THERMOCHIMICA ACTA, 1990, 163 :175-182

[7] RELATIVE REACTIVITIES OF FUNCTIONAL GROUPS INVOLVED IN SYNTHESIS OF POLY(PHENYLENE ETHER SULFONES) FROM HALOGENATED DERIVATIVES OF DIPHENYL SULFONE [J].

NEWTON, AB ;

ROSE, JB .

POLYMER, 1972, 13 (10) :465-&

[8]

PARODI F, 1988, ENCY POLYM SCI ENG, V13, P197

[9]

Parodi F., 1989, COMPREHENSIVE POLYM, V5, P561, DOI [10.1016/B978-0-08-096701-1.00174-9, DOI 10.1016/B978-0-08-096701-1.00174-9]

[10]

ROBERTS JD, 1964, BASIC PRINCIPLES ORG, P745

← 1 2 →