Metallization of polythiophenes .4. Interaction of vapor-deposited Cu and Ni with poly[3-(1,1,1,2,2,3,3,4,4,5,5,6,6-tridecafluorononyl)thiophene] (P3TT)

被引：10

作者：

Lachkar, A

Selmani, A

Sacher, E

Leclerc, M

机构：

[1] ECOLE POLYTECH,DEPT GENIE PHYS,MONTREAL,PQ H3C 3A7,CANADA

[2] UNIV MONTREAL,DEPT CHIM,MONTREAL,PQ H3C 3J7,CANADA

来源：

SYNTHETIC METALS | 1995年 / 75卷 / 03期

基金：

加拿大自然科学与工程研究理事会;

关键词：

metallization; poly[3-(1,1,1,2,2,3,3,4,4,5,5,6,6-tridecafluorononyl)thiophene; deposition;

D O I：

10.1016/0379-6779(96)80008-7

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

This article deals with the X-ray photoelectron spectroscopy (XPS) study of the interactions occurring during the formation of the interface between two transition metals, Ni and Cu, and the substituted polythiophene, poly [3-(1,1,1,2,2,3,3,4,4,5,5,6,6-tridecafluorononyl)thiophene] (P3TT). Ni was found to react to form both sulfide and fluoride. Cu was found to react mainly with S, forming only a negligible amount of fluoride. The results are consistent with the de-fluorination of the polymer substituent and the resultant formation of an unsaturated or crosslinked structure at the metal (Cu, Ni)/polymer interface.

引用

页码：195 / 200

页数：6

共 21 条

[1] LIGHT-EMITTING-DIODES BASED ON CONJUGATED POLYMERS [J].