DIMETHYLALLENEDIYL AS AN ETA-1,ETA-2-BRIDGING LIGAND IN A DIZIRCONOCENE COMPLEX

被引:23
作者
BINGER, P
LANGHAUSER, F
GABOR, B
MYNOTT, R
HERRMANN, AT
KRUGER, C
机构
关键词
D O I
10.1039/c39920000505
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Treatment of (eta-2-ethene)(trimethylphosphane)zirconocene 1 with 3,3-dimethylcyclopropene 2 leads to the formation of a new type of bis(ethylzirconocene) complex 3 with 3,3-dimethylallenediyl as a mu-1, mu-2-bridging ligand; the crystal structure of 3 is determined by X-ray analysis.
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页码:505 / 506
页数:2
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