MIXED BIPHOSPHINE COMPLEXES OF PALLADIUM(0) - THE STRUCTURE OF (BIS(DIPHENYLPHOSPHINO)ETHANE)-(BIS(DICYCLOHEXYLPHOSPHINO)ETHANE) PALLADIUM(0)

被引：26

作者：

BROADWOODSTRONG, GTL ^{[1
]}

CHALONER, PA ^{[1
]}

HITCHCOCK, PB ^{[1
]}

机构：

[1] UNIV SUSSEX,SCH CHEM & MOLEC SCI,BRIGHTON BN1 9QJ,E SUSSEX,ENGLAND

来源：

POLYHEDRON | 1993年 / 12卷 / 07期

关键词：

D O I：

10.1016/S0277-5387(00)81751-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A range of mixed biphosphine complexes of palladium(0) has been prepared and characterized by P-31 NMR spectroscopy. The complexes disproportionate in solution at rates which depend on the nature of the ligands. The structure of [Pd(dcpe)(dppe)] has been established in an X-ray diffraction study.

引用

页码：721 / 729

页数：9

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