HIGHLY HYDROGEN-DEFICIENT HYDROCARBON SPECIES FOR THE CO2-REFORMING OF CH4 ON CO/AL2O3 CATALYST

被引：34

作者：

OSAKI, T

MASUDA, H

HORIUCHI, T

MORI, T

机构：

[1] National Industrial Research Institute of Nagoya, Nagoya, 462, Hiratecho, Kitaku

来源：

CATALYSIS LETTERS | 1995年 / 34卷 / 1-2期

关键词：

CO2-REFORMING; CO/AL2O3; PULSE REACTION; RATE ANALYSIS; REACTION INTERMEDIATE;

D O I：

10.1007/BF00808322

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The dynamics of produced CO and H-2, measured by pulse surface reaction rate analysis (PSRA), revealed that the intermediate hydrocarbon species for the CO2-reforming of CH4 was highly hydrogen-deficient (CH0.75) on supported Co/Al2O3 catalyst. It was also found that the species was more reactive than the less hydrogen-deficient one (CH2.4) on Ni/Al2O3 catalyst.

引用

页码：59 / 63

页数：5

共 9 条

[1] ACTIVATION OF CH4 AND ITS REACTION WITH CO2 OVER SUPPORTED RH CATALYSTS [J].