STEROIDAL ALKALOIDS FROM ROOTS OF TOMATO STOCK

被引：19

作者：

NAGAOKA, T ^{[1
]}

YOSHIHARA, T ^{[1
]}

OHRA, J ^{[1
]}

SAKAMURA, S ^{[1
]}

机构：

[1] HOKKAIDO UNIV,FAC AGR,DEPT BIOSCI & CHEM,SAPPORO,HOKKAIDO 060,JAPAN

来源：

PHYTOCHEMISTRY | 1993年 / 34卷 / 04期

关键词：

LYCOPERSICON-ESCULENTUM X L-HIRSUTUM; SOLANACEAE; TOMATO STOCK; STEROIDAL ALKALOID; 5-ALPHA-TOMATIDAN-3-ONE; (23R)-23-ACETOXYTOMATIDINE; (23S)-23-ACETOXYSOLADULCIDINE; (23S; 25S)-23-ACETOXY-5-ALPHA; 22-ALPHA-N-SPIROSOLAN-3-BETA-O1; 22,26-EPIMINO-16-BETA,23-EPOXY-23-ALPHA-ETHOXY-5-ALPHA,25-ALPHA-H-CHOLEST-22(N)-ENE-3-BETA,20-ALPHA-DIOL; 22,26-EPIMINO-16-BETA,23-EPOXY-5-ALPHA,22-BETA-H,25-ALPHA-H-CHOLESTANE-3-BETA,23-ALPHA-DIOL;

D O I：

10.1016/S0031-9422(00)90734-9

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Six new steroidal alkaloids were isolated from roots of a hybrid of Lycopersicon esculentum x L. hirsutum and their structures elucidated as 5alpha-tomatidan-3-one, (23R)-23-acetoxytomatidine, (23S)-23-acetoxysoladulcidine, (23S,25S)-23-acetoxy-5alpha,22alphaN-spirosolan-3beta-ol; 22,26-epimino-16beta,23-epoxy-23alpha-ethoxy-5alpha,25alphaH-cholest-22(N)-ene-3beta,20alpha-diol and 22,26-epimino-16beta,23-epoxy-5alpha,22betaH,25alphaH-cholestane-3beta,23alpha-diol, respectively.

引用

页码：1153 / 1157

页数：5

共 14 条

[1] TRANSFORMATION OF TOMATIDINE BY GYMNOASCUS-REESII
BELIC, I
GABERCPOREKAR, V
SOCIC, H
ZAKELJ, M
[J]. ZEITSCHRIFT FUR ALLGEMEINE MIKROBIOLOGIE, 1982, 22 (06): : 359 - 363
[2] MICROBIAL DEHYDROGENATION OF TOMATIDINE
BELIC, I
SOCIC, H
[J]. JOURNAL OF STEROID BIOCHEMISTRY, 1972, 3 (05): : 843 - &
[3] ASSIGNMENT OF THE C-13 NMR-SPECTRA OF SOME 22,26-EPIMINOCHOLESTANES, 22,26-EPIMINOCHOLEST-22(N)-ENES AND SOME 3-BETA-AMINO STEROIDAL ALKALOIDS
BIRD, GJ
COLLINS, DJ
EASTWOOD, FW
EXNER, RH
[J]. AUSTRALIAN JOURNAL OF CHEMISTRY, 1979, 32 (04) : 797 - 816
[4] C-13 NMR-STUDIES .69. C-13 NMR-SPECTRA OF STEROIDS - SURVEY AND COMMENTARY
BLUNT, JW
STOTHERS, JB
[J]. ORGANIC MAGNETIC RESONANCE, 1977, 9 (08): : 439 - 464
[5] NMR STUDIES AND ABSOLUTE CONFIGURATION OF SOLANUM ALKALOIDS (SPIROAMINOKETAL ALKALOIDS)
BOLL, PM
VONPHILI.W
[J]. ACTA CHEMICA SCANDINAVICA, 1965, 19 (06): : 1365 - &
[6] SOLANUM ALKALOIDS .111. 3-DESAMINO-3-BETA-HYDROXYSOLANOCAPSINE - A STEROIDAL ALKALOID FROM SOLANUM-ACULEATUM
COLL, F
PREISS, A
BASTERECHEA, M
MOLA, JL
ADAM, G
[J]. PHYTOCHEMISTRY, 1983, 22 (09) : 2099 - 2100
[7] SOLANUM ALKALOIDS .112. ACULEAMINE, A SOLANOCAPSINE-TYPE STEROIDAL ALKALOID FROM SOLANUM-ACULEATUM
COLL, F
PREISS, A
BASTERECHEA, M
KUTSCHABSKY, L
MOLA, DL
SCHREIBER, K
ADAM, G
[J]. PHYTOCHEMISTRY, 1984, 23 (04) : 883 - 885
[8] LYCOPERSICONOLIDE, A STEROID LACTONE FROM TOMATO ROOTS
NAGAOKA, T
YOSHIHARA, T
SAKAMURA, S
[J]. PHYTOCHEMISTRY, 1987, 26 (07) : 2113 - 2114
[9] RADEGLIA R, 1977, TETRAHEDRON LETT, P903
[10] ISOLIERUNG VON NEBENALKALOIDEN UND 3BETA-HYDROXY-5ALPHA-PREGN-16-EN-20-ON AUS LYCOPERSICON PIMPINELLIFOLIUM MILL
SCHREIBE.K
AURICH, O
[J]. PHYTOCHEMISTRY, 1966, 5 (04) : 707 - &

← 1 2 →