ELECTROPHILIC ADDITIONS OF IODOSYLBENZENE ACTIVATED BY TRIFLUOROMETHANESULFONIC ACID, [PHIO-TFOH], TO ALKYNES

被引：61

作者：

KITAMURA, T

FURUKI, R

TANIGUCHI, H

STANG, PJ

机构：

[1] KYUSHU UNIV 36,FAC ENGN,DEPT CHEM SCI & TECHNOL,FUKUOKA 812,JAPAN

[2] UNIV UTAH,DEPT CHEM,SALT LAKE CITY,UT 84112

来源：

TETRAHEDRON | 1992年 / 48卷 / 35期

关键词：

D O I：

10.1016/S0040-4020(01)88255-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A reagent [PhIO-TfOH] prepared by mixing iodosylbenzene and triflic acid undergoes electrophilic addition to various alkynes under mild conditions. The addition is a highly stereoselective anti-addition and provides (E)-[beta-(trifluoromethanesulfonyloxy)vinyl]iodonium triflates in good to high yields.

引用

页码：7149 / 7156

页数：8

共 32 条

[1]

[Anonymous], REV HETEROATOM CHEM

[2] SYNTHESIS OF ALKYNYL(PHENYL)IODONIUM TRIFLATES AND THEIR REACTION WITH DIETHYL 2-AMINOMALONATE [J].