SPIN CATALYSIS - 3-SPIN MODEL

被引：23

作者：

BUCHACHENKO, AL

BERDINSKY, VL

机构：

[1] N.N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, 117977 Moscow

来源：

CHEMICAL PHYSICS LETTERS | 1995年 / 242卷 / 1-2期

关键词：

D O I：

10.1016/0009-2614(95)00726-K

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Recently it has been shown that in a radical triad one of the radical partners affects the chemical reactivity of the other pair, catalyzing the spin transformation of this pair. The phenomenon is shown to be caused by the exchange interaction between the radical triad partners which stimulates doublet-doublet spin evolution and produces the oscillating triplet-singlet spin conversion of the selected radical pair in the radical triad under the influence of the odd radical spin. The theory of the phenomenon is developed and the equations for the rate of spin evolution in a three-spin system are derived. A new type of quantum beats is predicted.

引用

页码：43 / 47

页数：5

共 11 条

[1]

BERDINSKY VL, 1991, PREPRINT I CHEM PHYS

[2]

Buchachenko A.L., 1994, CHEM GENERATION RECE

[3]

BUCHACHENKO AL, 1991, RUSS CHEM REV, V62, P1073

[4]

BUCHACHENKO AL, 1995, CHEM PHYS LETT, V223, P315

[5] ELECTRON-SPIN POLARIZATION IN A 3-ELECTRON SPIN SYSTEM - AN APPLICATION TO BACTERIAL PHOTOSYNTHESIS [J].

HOFF, AJ ;

HORE, PJ .

CHEMICAL PHYSICS LETTERS, 1984, 108 (01) :104-110

[6]

HORE PJ, 1989, ADV EPR APPL BIOL BI, P405

[7]

LANDAU LD, 1963, QUANTUM MECHANICS

[8]

Magnus W., 1976, COMBINATORIAL GROUP

[9]

Molin Y. N., 1980, PRINCIPLES APPL CHEM

[10]

Salikhov K. M., 1984, SPIN POLARIZATION MA

← 1 2 →