EXTRACTION OF COPPER FROM ACID CHLORIDE SOLUTIONS BY N-ALKYL-3-PYRIDINECARBOXAMIDES AND N,N-DIALKYL-3-PYRIDINECARBOXAMIDES

被引：45

作者：

BOROWIAK-RESTERNA, A

机构：

[1] Institute of Chemical Technology and Engineering Poznań Technical University, PI. M.Sklodowskiej-Curie 2

来源：

SOLVENT EXTRACTION AND ION EXCHANGE | 1994年 / 12卷 / 03期

关键词：

D O I：

10.1080/07366299408918224

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Model individual N-alkyl-3-pyridinecarboxamides and N,N-di-alkyl-3-pyridinecarboxamides were synthesized and used for copper(II) extraction from chloride solutions. The stoichiometry of its reaction with copper(II) in chloride media was determined. N-alkyl-3-pyridinecarboxamides are stronger extractants than N,N-dialkyl-3-pyridinecarboxamides but N-alkyl-3-pyridinecarboxamides and their complexes are slightly dissolved in the hydrocarbon diluents.

引用

页码：557 / 569

页数：13

共 13 条

[1] NICOTINIC ACID - WATER-INSOLUBLE ESTERS AND AMIDES
BADGETT, CO
PROVOST, RC
OGG, CL
WOODWARD, CF
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1945, 67 (07) : 1135 - 1138
[2] DALTON RF, 1983, P ISEC 83 DENVER, P189
[3] DANIELSSEN T, 1983, P INT SOLV EXTR C IS, P536
[4] SYNTHESIS, STRUCTURE AND PROPERTIES OF THE ISOMERIC DINUCLEAR COMPLEXES [(DENC)2CUX2]2(DENC=N,N-DIETHYLNICOTINAMIDE,X=CL OR BR) AND THE KINETICS OF THEIR REACTIONS WITH DENC IN METHYLENE-CHLORIDE
DAVIES, G
ELTOUKHY, A
ONAN, KD
VEIDIS, M
[J]. INORGANICA CHIMICA ACTA-ARTICLES AND LETTERS, 1985, 98 (02): : 85 - 94
[5] DUPREEZ JGH, 1980, S AFR J CHEM, V33, P9
[6] DUPREEZ JGH, 1974, INORG NUCL CHEM LETT, V10, P935
[7] MARCZENKO Z, 1979, SPEKTROFOTOMETRYCZNE, P405
[8] PRICE R, 1982, JONIT EEC CANADA SEM
[9] SOLVENT-EXTRACTION OF COPPER(II) FROM CHLORIDE SOLUTIONS BY SOME PYRIDINE CARBOXYLATE ESTERS
SOLDENHOFF, KH
[J]. SOLVENT EXTRACTION AND ION EXCHANGE, 1987, 5 (05) : 833 - 851
[10] SOLDENHOFF KH, 1986, P ISEC 86 MUN GERM, V2, P123

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