SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF A NEW RARE-EARTH SELENODIPHOSPHATE(IV) - KLAP2SE6

被引：50

作者：

CHEN, JH ^{[1
]}

DORHOUT, PK ^{[1
]}

机构：

[1] COLORADO STATE UNIV,DEPT CHEM,FT COLLINS,CO 80523

来源：

INORGANIC CHEMISTRY | 1995年 / 34卷 / 23期

关键词：

D O I：

10.1021/ic00127a003

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The high-temperature, molten alkali-metal polyselenide salt reaction of the elements yielded a new, porous-layered rare-earth selenodiphosphate(IV), KLaP2Se6, that comprises uniquely bound [P2Se6](4-) units that bind lanthanum atoms through face-capping interactions. This is the first known rare-earth selenodiphosphate(IV) compound.

引用

页码：5705 / &

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