SILICON-CARBON UNSATURATED-COMPOUNDS .46. NICKEL-CATALYZED REACTION OF 2-TOLYLHEXAMETHYLTRISILANES AND 2-PHENYL-2-(PHENYLETHYNYL) HEXAMETHYLTRISILANES IN THE PRESENCE OF 2,3-DIMETHYLBUTADIENE AND DICYCLOPENTADIENE

被引：13

作者：

KUNAI, A ^{[1
]}

YUZURIHA, Y ^{[1
]}

NAKA, A ^{[1
]}

ISHIKAWA, M ^{[1
]}

机构：

[1] HIROSHIMA UNIV,FAC ENGN,DEPT APPL CHEM,HIROSHIMA 724,JAPAN

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 455卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(93)80383-M

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of 2-phenyl-2-(phenylethynyl)-hexamethyltrisilane (1a) with 2,3-dimethylbutadiene in the presence of Ni(cod)2 at 200-degrees-C for 20 h gave 1-[2,3-dimethyl-4-(trimethylsilyl)-2-butenyl]-1-phenyl-1-(phenylethynyl)trimethyldisilane and bis[2,3-dimethyl-4-(trimethylsilyl)-2-butenyl]phenyl(phenylethynyl)silane, while treatment of 1a with dicyclopentadiene in the presence of Ni(cod)2 gave an isomerization product, 1-phenyl-1,2-bis(trimethylsilyl)-1-silaindene. Similar reactions of 2-phenylethynyl-2-o-tolyl-hexa-methyltrisilane, 2-phenylethynyl-2-m-tolylhexamethyltrisilane, and 2-phenylethynyl-2-p-tolylhexamethyltrisilane are also described.

引用

页码：77 / 81

页数：5

共 5 条

[1] SILICON CARBON UNSATURATED-COMPOUNDS .18. NICKEL-CATALYZED REACTIONS OF (PHENYLETHYNYL)POLYSILANES WITH PHENYL(TRIMETHYLSILYL)ACETYLENE AND MOLECULAR-STRUCTURE OF 3-PHENYL-4-[PHENYL(TRIMETHYLSILYL)METHYLENE]-1,1,2-TRIS(TRIMETHYLSILYL)-1-SILACYCLOBUT-2-ENE [J].

ISHIKAWA, M ;

MATSUZAWA, S ;

HIROTSU, K ;

KAMITORI, S ;

HIGUCHI, T .

ORGANOMETALLICS, 1984, 3 (12) :1930-1932

[2] SILICON CARBON UNSATURATED-COMPOUNDS .19. NICKEL-CATALYZED REACTIONS OF SILACYCLOPROPENES AND (PHENYLETHYNYL)POLYSILANES WITH PHENYL(TRIMETHYLSILYL)ACETYLENE AND MOLECULAR-STRUCTURE OF 1,4,4-TRIMETHYL-3,6-DIPHENYL-1,2,5-TRIS(TRIMETHYLSILYL)-1,4-DISILACYCLOHEXA-2,5-DIENE [J].

ISHIKAWA, M ;

MATSUZAWA, S ;

HIGUCHI, T ;

KAMITORI, S ;

HIROTSU, K .

ORGANOMETALLICS, 1985, 4 (11) :2040-2046

[3] SILICON-CARBON UNSATURATED-COMPOUNDS .21. ISOMERIZATION OF A 1-SILAPROPADIENE IN THE PRESENCE OF TETRAKIS(TRIETHYLPHOSPHINE)NICKEL(0) [J].

ISHIKAWA, M ;

OHSHITA, J ;

ITO, Y .

ORGANOMETALLICS, 1986, 5 (07) :1518-1519

[4] SILICON CARBON UNSATURATED-COMPOUNDS .27. NICKEL-CATALYZED REACTIONS OF 2-PHENYL-2-(PHENYLETHYNYL)HEXAMETHYLTRISILANE 2-(ORTHO-TOLYL)-2-(PHENYLETHYNYL)HEXAMETHYLTRISILANE [J].

ISHIKAWA, M ;

NOMURA, Y ;

TOZAKI, E ;

KUNAI, A ;

OHSHITA, J .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 399 (1-2) :205-213

[5] SILICON CARBON UNSATURATED-COMPOUNDS .45. REACTION OF BENZOYLTRIS(TRIMETHYLSILYL)SILANE WITH ARYLLITHIUM REAGENTS [J].

OHSHITA, J ;

MASAOKA, Y ;

ISHIKAWA, M ;

TAKEUCHI, T .

ORGANOMETALLICS, 1993, 12 (03) :876-879

← 1 →