THE 1ST IMINO-LEAD COMPLEX - SYNTHESIS AND X-RAY CHARACTERIZATION OF PB[MU-N=C(BU(T))PH](3)LITHF (THF = TETRAHYDROFURAN)

被引：15

作者：

EDWARDS, AJ ^{[1
]}

PAVER, MA ^{[1
]}

RAITHBY, PR ^{[1
]}

RUSSELL, CA ^{[1
]}

WRIGHT, DS ^{[1
]}

机构：

[1] UNIV CAMBRIDGE,CHEM LAB,LENSFIELD RD,CAMBRIDGE CB2 1EW,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 13期

关键词：

D O I：

10.1039/c39930001086

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound, Pb[N=C(But)Ph]3Li.thf, has been synthesised by nucleophilic substitution of (C5H5)2 Pb (1 equiv.) with LiN=C(Bu(t))(Ph) (2 equiv.) and shown by X-ray crystallography to have a distorted trigonal bipyramidal PbN3Li core structure in which the phenyl groups of the imino ligands face towards, and encircle, the Pb.

引用

页码：1086 / 1088

页数：3

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