CATALYTIC ENANTIOSELECTIVE C-C COUPLING - ALLYL TRANSFER AND MUKAIYAMA ALDOL REACTION

被引：146

作者：

BACH, T

机构：

[1] Organisch-chemisches Institut, Universität Münster, D-48149

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 04期

关键词：

D O I：

10.1002/anie.199404171

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

To obtain enantiomerically pure products without using stoichiometric quantities of chiral components is now possible for the title reactions [Eq. (a)]. Chiral Lewis acids M′Xn are employed, which enable an excellent facial differentiation. In some cases these catalysts provide enantiomeric excesses greater than 95% and outstanding chemical yields. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：417 / 419

页数：3

共 29 条

[1] ENANTIOSELECTIVE MUKAIYAMA-ALDOL AND ALDOL-DIHYDROPYRONE ANNULATION REACTIONS CATALYZED BY A TRYPTOPHAN-DERIVED OXAZABOROLIDINE
COREY, EJ
CYWIN, CL
ROPER, TD
[J]. TETRAHEDRON LETTERS, 1992, 33 (46) : 6907 - 6910
[2] THE ORIGIN OF GREATER THAN 200/1 ENANTIOSELECTIVITY IN A CATALYTIC DIELS-ALDER REACTION AS REVEALED BY PHYSICAL AND CHEMICAL STUDIES
COREY, EJ
LOH, TP
ROPER, TD
AZIMIOARA, MD
NOE, MC
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (21) : 8290 - 8292
[3] CATALYTIC ASYMMETRIC-SYNTHESIS OF HOMOALLYLIC ALCOHOLS
COSTA, AL
PIAZZA, MG
TAGLIAVINI, E
TROMBINI, C
UMANIRONCHI, A
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (15) : 7001 - 7002
[4] ASYMMETRIC BORON-CATALYZED REACTIONS
DELOUX, L
SREBNIK, M
[J]. CHEMICAL REVIEWS, 1993, 93 (02) : 763 - 784
[5] Fleming I., 1991, COMPREHENSIVE ORGANI, P563
[6] FURUTA K, 1991, SYNLETT, P439
[7] FURUTA K, 1991, SYNLETT, P561
[8] CATALYTIC ASYMMETRIC ALDOL REACTIONS - USE OF A CHIRAL (ACYLOXY)BORANE COMPLEX AS A VERSATILE LEWIS ACID CATALYST
FURUTA, K
MARUYAMA, T
YAMAMOTO, H
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (03) : 1041 - 1042
[9] Gennari C., 1991, COMPREHENSIVE ORGANI, V2, P629, DOI DOI 10.1016/B978-0-08-052349-1.00043-3
[10] Heathcock C. H., 1991, COMPREHENSIVE ORGANI, V1, P133

← 1 2 3 →