STRUCTURAL STUDY OF ALKALOIDS FROM SECURIDACA-LONGIPEDUNCULATA ROOTS .2. ISOLATION AND CHARACTERIZATION BY SUPERCRITICAL-FLUID CHROMATOGRAPHY MASS-SPECTROMETRY

被引：17

作者：

SCANDOLA, M

GAMES, DE

COSTA, C

ALLEGRI, G

BERTAZZO, A

CURCURUTO, O

TRALDI, P

机构：

[1] CNR, AREA RIC, I-35020 PADUA, ITALY

[2] UNIV COLL SWANSEA, SWANSEA SA2 8PP, W GLAM, WALES

[3] UNIV PADUA, CNR, CTR STUDIO CHIM FARM, DIPARTIMENTO SCI FARMACEUT, I-35131 PADUA, ITALY

来源：

JOURNAL OF HETEROCYCLIC CHEMISTRY | 1994年 / 31卷 / 01期

关键词：

D O I：

10.1002/jhet.5570310137

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Various alkaloids obtained from the methanol extracts of the roots of Securidaca Longipedunculata Fres. were studied using supercritical fluid chromatography/mass spectrometry. This hyphenated method and parallel unimolecular and collisionally activated decomposition experiments on electron impact-generated molecular ions gave information on the structure of compounds. The presence of the ergoline skeleton in some of them was assigned.

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页码：219 / 224

页数：6

相关论文

共 23 条

[1] COMBINED LIQUID-CHROMATOGRAPHY MASS-SPECTROMETRY .1. COUPLING BY MEANS OF A MOVING BELT INTERFACE [J].

ARPINO, P .

MASS SPECTROMETRY REVIEWS, 1989, 8 (01) :35-55

[2] FAST ATOM BOMBARDMENT OF SOLIDS (FAB) - A NEW ION-SOURCE FOR MASS-SPECTROMETRY [J].

BARBER, M ;

BORDOLI, RS ;

SEDGWICK, RD ;

TYLER, AN .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1981, (07) :325-327

[3] SUPERCRITICAL FLUID CHROMATOGRAPHIC AND SUPERCRITICAL FLUID CHROMATOGRAPHIC MASS-SPECTROMETRIC STUDIES OF SOME POLAR COMPOUNDS [J].

BERRY, AJ ;

GAMES, DE ;

PERKINS, JR .

JOURNAL OF CHROMATOGRAPHY, 1986, 363 (02) :147-158

[4] PACKED-COLUMN SUPERCRITICAL FLUID CHROMATOGRAPHY-MASS SPECTROMETRY USING A THERMOSPRAY SOURCE IN THE FILAMENT-ON MODE [J].

BERRY, AJ ;

GAMES, DE ;

MYLCHREEST, IC ;

PERKINS, JR ;

PLEASANCE, S .

BIOMEDICAL AND ENVIRONMENTAL MASS SPECTROMETRY, 1988, 15 (02) :105-109

[5]

BERRY AJ, 1986, ANAL P, V23, P451

[6]

Budzikiewicz H., 1982, MASS SPECTROM REV, V1, P125

[7]

BUDZIKIEWICZ H, 1964, STRUCTURE ELUCIDATIO, V1, P233

[8]

Cooks R. G, 1978, COLLISION SPECTRSCOP, P458

[9] GAS-CHROMATOGRAPHIC MASS-SPECTROMETRIC INVESTIGATION OF THE VOLATILE MAIN COMPONENTS FROM ROOTS OF SECURIDACA-LONGIPEDUNCULATA [J].

COSTA, C ;

BERTAZZO, A ;

BIASIOLO, M ;

ALLEGRI, G ;

CURCURUTO, O ;

TRALDI, P .

ORGANIC MASS SPECTROMETRY, 1992, 27 (03) :255-256

[10] INDOLE ALKALOIDS FROM THE ROOTS OF AN AFRICAN PLANT SECURIDACA-LONGIPEDUNCULATA .1. ISOLATION BY COLUMN CHROMATOGRAPHY AND PRELIMINARY STRUCTURAL CHARACTERIZATION BY MASS-SPECTROMETRY [J].

COSTA, C ;

BERTAZZO, A ;

ALLEGRI, G ;

CURCURUTO, O ;

TRALDI, P .

JOURNAL OF HETEROCYCLIC CHEMISTRY, 1992, 29 (06) :1641-1647