Tritium release from various neutron-irradiated samples of lithium meta- and orthosilicate has been studied in annealing experiments. Some of the samples have previously been tested in-pile. The temperature has been varied systematically and the influence of purge gas composition, flow rate and pressure and of moisture in the purge gas and samples has been tested. In agreement with previous results, release from orthosilicate was found to be faster than from metasilicate. The experimental release has been compared with theoretical predictions assuming various processes (diffusion, trapping, recombination). These comparisons and other evidence indicate that the tritium release in our out-of-pile tests, especially from the orthosilicate samples, is mainly determined by moisture in the samples and/or the purge gas.