THE CRYSTAL-STRUCTURE OF TETRAETHYLAMMONIUM AQUATETRACYANOOXORHENATE(V)

被引：31

作者：

PURCELL, W ^{[1
]}

ROODT, A ^{[1
]}

BASSON, SS ^{[1
]}

LEIPOLDT, JG ^{[1
]}

机构：

[1] UNIV ORANGE FREE STATE,DEPT CHEM,BLOEMFONTEIN 9300,SOUTH AFRICA

来源：

TRANSITION METAL CHEMISTRY | 1990年 / 15卷 / 03期

关键词：

D O I：

10.1007/BF01038383

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The crystal structure of the tetraethylammonium salt of [ReO(H2O)(CN)4]- has been determined from threedimensional x-ray diffraction data. The light blue crystals are monoclinic, space group P21/m with a=8.760(1), b=9.518(5), c=11.718(1) Å, β=102.63(1)o with two molecules per unit cell. The final R value using 2009 observed reflections and anisotropic thermal parameters for all the non-hydrogen atoms was 0.038. The [ReO(H2O)(CN)4]- ion has a distorted octahedral geometry with the rhenium atom displaced by 0.30 Å out of the plane formed by the four carbon atoms of the cyano ligands towards the oxo ligand. Bond distances: Re=O=1.667(8), Re-OH2=2.142(7) and Re-C (average)=2.11(1) Å. © 1990 Chapman and Hall Ltd.

引用

页码：239 / 241

页数：3

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