CHARACTERIZATION OF PRECIOUS METAL PARTICLES PREPARED USING CHITOSAN AS A PROTECTIVE AGENT

被引:32
作者
ISHIZUKI, N
TORIGOE, K
ESUMI, K
MEGURO, K
机构
[1] SCI UNIV TOKYO, DEPT APPL CHEM, SHINJUKU KU, TOKYO 162, JAPAN
[2] SCI UNIV TOKYO, INST COLLOID & INTERFACE SCI, SHINJUKU KU, TOKYO 162, JAPAN
来源
COLLOIDS AND SURFACES | 1991年 / 55卷
关键词
D O I
10.1016/0166-6622(91)80079-4
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Precious metal particles (Au, Pt, Pd, Rh) were prepared using chitosan as a protective agent. The particle sizes decreased with increasing amounts of chitosan, while the dispersion stability against electrolyte increased. Similarly, stable bimetallic particles of Au-Pd and Au-Rh were obtained and their particle sizes were almost independent of feed composition. Furthermore, these bimetallic particles exhibited characteristic properties for the decomposition of hydrogen peroxide and hydrogenation of methylvinylketone.
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页码:15 / 21
页数:7
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