AN UNCOMPLEXED 1,2,3-TRIBOROLANE DERIVATIVE

被引：6

作者：

MELLER, A

BROMM, D

MARINGGELE, W

HEINE, A

STALKE, D

SHELDRICK, GM

机构：

[1] Institut Für Anorganische Chemie, Universität Göttingen, Göttingen, D-3400

来源：

CHEMISCHE BERICHTE | 1990年 / 123卷 / 02期

关键词：

1,2,3‐Triborolane / Dicyclopentadiene / Dichloro(diisopropylamino)borane, dehalogenation product of / Triborane(5), 1,2,3‐tris(diisopropylamino)‐;

D O I：

10.1002/cber.19901230212

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(3α,4β,4aβ,7aβ,8β,8aα)‐1,2,3‐Tris(diisopropylamino)‐1,2,3,3a,44a,5,7a,8,8a‐decahydro‐4,8‐methanoindeno[5,6‐d]‐1,2,3‐triborol (1) is formed from dicyclopentadiene and dichloro(diisopropylamino)borane upon treatment with sodium/potassium alloy in hexane. 1,2,3‐Tris(diiso propylamino)triborane(5) (2) was also obtained. 1 is characterized by elemental analyses, spectroscopic data, and by an X‐ray structure analysis, 2 by its MS and NMR data. Copyright © 1990 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim

引用

页码：293 / 294

页数：2

共 9 条

[1]

BROMM D, 1986, THESIS U GOTTINGEN

[2]

Franz D.A., 1970, J AM CHEM SOC, V92, P1438

[3] STRUCTURE AND STEREOCHEMISTRY IN METALLOBORON CAGE COMPOUNDS [J].