TEMPERATURE-DEPENDENCE OF DOUBLE-LAYER PARAMETERS OF THE SILVER (100) FACE - COMPARISON WITH OTHER SILVER FACES

被引：17

作者：

DOUBOVA, LM

HAMELIN, A

STOICOVICIU, L

TRASATTI, S

机构：

[1] CNRS,ELECTROCHIM INTERFACIALE LAB,F-92195 MEUDON,FRANCE

[2] UNIV MILAN,DEPT PHYS CHEM & ELECTROCHEM,I-20133 MILAN,ITALY

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1992年 / 325卷 / 1-2期

关键词：

D O I：

10.1016/0022-0728(92)80112-H

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The temperature coefficient of the zero charge potential of the Ag(100) face in KPF6 solutions has been found to be positive, while the capacitance has a negative temperature coefficient at this potential. The entropy of formation of the double layer has been determined as a function of the charge density on the metal for 5, 10 and 20 mM solutions. The temperature coefficients of the (100) silver face have been compared with those of the (111) and (110) faces.

引用

页码：197 / 205

页数：9

共 24 条

[1] THE DEPENDENCE OF THE POTENTIAL OF ZERO CHARGE OF SILVER ELECTRODES ON THE CRYSTALLOGRAPHIC ORIENTATION OF THE SURFACE [J].