THE SYNTHESIS OF NATURAL ACETYLENIC-COMPOUNDS FROM EUTYPA-LATA (PERS-F)TUL

被引：30

作者：

DEFRANQ, E ^{[1
]}

ZESIGER, T ^{[1
]}

TABACCHI, R ^{[1
]}

机构：

[1] UNIV NEUCHATEL, INST CHIM, AVE BELLEVAUX 51, CH-2000 NEUCHATEL, SWITZERLAND

来源：

HELVETICA CHIMICA ACTA | 1993年 / 76卷 / 01期

关键词：

D O I：

10.1002/hlca.19930760126

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of a series of novel acetylenic compounds 1-7, isolated recently from the fungus Eutypa lata, is described. The crucial step is the coupling reaction between a protected aryl halogenide and the acetylenic chain as a cuprous acetylide (Scheme 1). A more efficient method using bis(triphenylphosphine)palladium dichloride ([Pd(PPh3)2Cl2]) as catalyst was also carried out with success.

引用

页码：425 / 430

页数：6

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