REGIOSELECTIVE REACTIONS OF TRIMETHYLSILYLPROPARGYLIC AND TRIMETHYLSILYLALLYLIC ORGANOANTIMONY COMPOUNDS WITH ALDEHYDES

被引：12

作者：

ZHANG, LJ ^{[1
]}

MO, XS ^{[1
]}

HUANG, JL ^{[1
]}

HUANG, YZ ^{[1
]}

机构：

[1] CHINESE ACAD SCI,SHANGHAI INST ORGAN CHEM,ORGANOMET CHEM LAB,345 LINGLING LU,SHANGHAI 200032,PEOPLES R CHINA

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 10期

关键词：

D O I：

10.1016/0040-4039(93)85024-Q

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reactions of trimethylsilylallylic organoantimony compound with aldehydes show very high selectivity favoring alpha-adducts; and the reactions of trimethylsilylpropargylic organoantimony compounds with aldehydes also exhibit very high acetylenic selectivity (alpha-adducts) in the presence of LiBr.

引用

页码：1621 / 1624

页数：4

共 3 条

[1] SILANES IN ORGANIC-SYNTHESIS .11. REGIOCONTROLLED SYNTHESIS OF ALPHA-HYDROXYMETHYLATED (TRIMETHYLSILYL)ALLENES [J].