SELF-DIFFUSION STUDY OF COPPER HALIDES USING TRACER METHODS

被引：15

作者：

ZHENGJOHANSSON, JXM ^{[1
]}

SKOLD, K ^{[1
]}

JORGENSEN, JE ^{[1
]}

机构：

[1] AARHUS UNIV,DEPT CHEM,DK-8000 AARHUS,DENMARK

来源：

SOLID STATE IONICS | 1994年 / 70卷

关键词：

D O I：

10.1016/0167-2738(94)90365-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Tracer diffusion results for Cu-64 in the three solid phases of CuBr are presented and the results for CuX (X = Cl, Br, I) obtained in this and earlier studies are summarised. All three systems reach diffusion levels of (3-4) X 10(-5) cm2/s. The Cu diffusion displays a non-bonding energy dependence. The sequential change in anion sizes and masses and a consequent modification in diffusion paths are used to interpret the irregular diffusion.

引用

页码：522 / 527

页数：6

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