CRYSTAL-STRUCTURE ANALYSIS OF AN OSMIUM(VI) BISGLYCOLATE PRODUCED BY REACTION OF A STERICALLY HINDERED CHIRAL NONRACEMIC ALKENE WITH OSMIUM-TETROXIDE

被引：17

作者：

SIVIK, MR ^{[1
]}

GALLUCCI, JC ^{[1
]}

PAQUETTE, LA ^{[1
]}

机构：

[1] OHIO STATE UNIV,EVANS CHEM LABS,COLUMBUS,OH 43210

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1990年 / 55卷 / 01期

关键词：

D O I：

10.1021/jo00288a079

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Osmium tetroxide is widely recognized to be the premier reagent for accomplishing clean syn-dihydroxylation of carbon-carbon double bonds.2 Since introduction of the process by Criegee in 1936,3 several mechanistic investigations of stoichiometric level reactions have appeared.4 More recently, Sharpless and his co-workers have attempted to gain detailed insight into the course of chi-ral-catalyzed asymmetric variants to this serviceable re-action.5 A detailed kinetic study by Erdik and Matteson of 0s04-catalyzed trimethylamine N-oxide oxidations has also just appeared.6 N-Methylmorpholine N-oxide (NMO) constitutes an excellent alternative oxidizing agent7. © 1990, American Chemical Society. All rights reserved.

引用

页码：391 / 393

页数：3

共 25 条

[1]

ATOVMYAN LO, 1979, ZH STRUKT KHIM, V20, P754

[2]

BEURSKENS PT, 19841 CRYST LAB TECH

[3] X-RAY MOLECULAR-STRUCTURE OF ASYMMETRICALLY BRIDGED ESTER COMPLEX DI-MU-OXO-BIS[(CYCLOHEXANE-1,2-DIOLATO)OXO(QUINUCLIDINE)OSMIUM(VI)], [OSO2(O2C6H10)(C7H13N)]2 [J].