SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF [PD(C6F5)(ETA2-((PH2P)3C))(PPH3)], A MONONUCLEAR COMPOUND CONTAINING ETA2-TRIS(DIPHENYLPHOSPHINE)METHANIDE

被引：8

作者：

FORNIES, J

MARTINEZ, F

NAVARRO, R

URRIOLABEITIA, EP

机构：

[1] Departamento de Química Inorgánica, Instituto de Ciencia de Materiales de Aragón, Universidad de Zaragoza

来源：

POLYHEDRON | 1990年 / 9卷 / 17期

关键词：

D O I：

10.1016/S0277-5387(00)84052-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction between [Pd(C6F5)(acac)(PPh3)] and (Ph2P)3CH in CH2Cl2 affords [Pd(C6F5)(η2-{(Ph2P)3C})(PPh3)] (1) which can be protonated by HBF4 to yield [Pd(C6F5)(η2-{(Ph2P)3CH})(PPh3)](BF4) (2). The X-ray structure determination of complex 1 reveals a distorted square-planar environment for the metal centre with an η2-coordination of the tris(diphenylphosphino)methanide, the skeletal P3C group of this ligand is moderately distorted from a C(sp2) arrangement. © 1990.

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页码：2181 / 2183

页数：3

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