SELECTIVE EXCITATION OF DEUTERIUM POWDER PATTERNS FOR STUDIES OF MOLECULAR-MOTION IN SOLIDS

被引：14

作者：

LIN, TH ^{[1
]}

VOLD, RR ^{[1
]}

机构：

[1] UNIV CALIF SAN DIEGO,DEPT CHEM,LA JOLLA,CA 92093

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1991年 / 95卷 / 23期

关键词：

D O I：

10.1021/j100176a003

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The rate of internal rotation of the amino group in solid p-nitroaniline-N,N-d2 has been determined from NMR "hole-burning" experiments. This work represents the first use of quantitative simulations of selectively perturbed deuterium powder patterns and the results demonstrate the potential of this technique for characterization of molecular motion in solids.

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页码：9032 / 9034

页数：3

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