POTENTIOMETRIC RESPONSE OF PVC CROWN-ETHER MEMBRANE ELECTRODES TO NONIONIC ORGANIC-COMPOUNDS

被引：4

作者：

ANZAI, J

LIU, CC

机构：

[1] Electronics Design Center, Case Western Reserve University, Cleveland

来源：

SENSORS AND ACTUATORS B-CHEMICAL | 1991年 / 5卷 / 1-4期

关键词：

Alcohols - Sensors - Ethers - Crown Ethers - Membranes - Polymeric - Organic Compounds - Sensors - Polyvinyl Chlorides;

D O I：

10.1016/0925-4005(91)80240-K

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The potentiometric response of PVC/dicyclohexyl-18-crown-6 membrane ion sensors to nonionic alcohols has been measured. The ion sensors are potentiometrically sensitive to lipophilic alcohols such as 1-hexanol, 1-heptanol, 1-octanol, and 1-nonanol at the millimolar level or lower, whereas low-lipophilicity alcohols, including methanol, ethanol, ethylene glycol, diethylene glycol, and 1,3-propanediol, have no influence on the sensor response. The results are discussed in terms of specific adsorption and penetration of the alcohols to the PVC/crown ether membrane.

引用

页码：171 / 172

页数：2