PREDICTION OF CHROMATOGRAPHIC RETENTION OF METAL-COMPLEXES FROM STABILITY-CONSTANTS MEASURED BY ION CHROMATOGRAPHY

被引：12

作者：

ALUMAA, P ^{[1
]}

PENTSUK, J ^{[1
]}

机构：

[1] TARTU STATE UNIV,INST CHEM PHYS,TARTU 202400,ESTONIA

来源：

CHROMATOGRAPHIA | 1994年 / 38卷 / 9-10期

关键词：

ION CHROMATOGRAPHY; OPTIMIZATION; STABILITY CONSTANTS OF METAL COMPLEXES; RETENTION PREDICTION;

D O I：

10.1007/BF02277155

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

A theoretical model is used to predict retention times of divalent metal cations in single-column ion chromatography using one or more ligands in the eluent. Stability constants for complexes of divalent metal cations with citric and tartaric acid were measured by ion chromatography. A basis for optimization of single-column ion chromatography employing the KATIEKS-S column and ethylenediammonium citrate and tartrate eluents has been established.

引用

页码：566 / 570

页数：5

共 9 条

[1] ARATSKOVA AA, 1984, ZH ANAL KHIM, V44, P2060
[2] SEPARATION OF THE LANTHANIDES ON HIGH-EFFICIENCY BONDED PHASES AND CONVENTIONAL ION-EXCHANGE RESINS
ELCHUK, S
CASSIDY, RM
[J]. ANALYTICAL CHEMISTRY, 1979, 51 (09) : 1434 - 1438
[3] Haddad P. R., 1990, ION CHROMATOGRAPHY P
[4] DETERMINATION OF STABILITY-CONSTANTS OF METAL-COMPLEXES FROM ION-CHROMATOGRAPHIC MEASUREMENTS
JANOS, P
[J]. JOURNAL OF CHROMATOGRAPHY, 1993, 641 (02): : 229 - 234
[5] MEASUREMENT OF STABILITY-CONSTANTS FOR COMPLEXES OF DIVALENT-CATIONS WITH TARTARIC ACID BY ION CHROMATOGRAPHY
LIN, FHJ
HORVATH, C
[J]. JOURNAL OF CHROMATOGRAPHY, 1992, 589 (1-2): : 185 - 195
[6] EFFECT OF COMPLEXING AGENTS ON THE CHROMATOGRAPHIC-SEPARATION OF POLYVALENT CATIONS
SEVENICH, GJ
FRITZ, JS
[J]. JOURNAL OF CHROMATOGRAPHY, 1985, 347 (01): : 147 - 154
[7] SEVENICH GJ, 1986, J CHROMATOGR, V371, P361
[8] ADDITION OF COMPLEXING AGENTS IN ION CHROMATOGRAPHY FOR SEPARATION OF POLYVALENT METAL-IONS
SEVENICH, GJ
FRITZ, JS
[J]. ANALYTICAL CHEMISTRY, 1983, 55 (01) : 12 - 16
[9] NOVEL ION-EXCHANGE CHROMATOGRAPHIC METHOD USING CONDUCTIMETRIC DETECTION
SMALL, H
STEVENS, TS
BAUMAN, WC
[J]. ANALYTICAL CHEMISTRY, 1975, 47 (11) : 1801 - 1809

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