PRECIPITATION POLYMERIZATION OF ACRYLIC-ACID IN SUPERCRITICAL CARBON-DIOXIDE

被引：127

作者：

ROMACK, TJ ^{[1
]}

MAURY, EE ^{[1
]}

DESIMONE, JM ^{[1
]}

机构：

[1] UNIV N CAROLINA,DEPT CHEM,VENABLE LABS,CHAPEL HILL,NC 27599

来源：

MACROMOLECULES | 1995年 / 28卷 / 04期

关键词：

D O I：

10.1021/ma00108a017

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

We report the successful precipitation polymerization of acrylic acid in supercritical carbon dioxide at pressures ranging from 125 to 345 bar utilizing AIBN as a free radical initiator. Analyses by gel permeation chromatograpy (GPC) and scanning electron microscopy (SEM) indicate that for the pressure range studied there is no appreciable effect on product molecular weight, molecular weight distribution, or particle size or morphology. In addition, effective molecular weight control was demonstrated for precipitation polymerizations of acrylic acid in CO2 through the use of ethyl mercaptan as a chain transfer agent.

引用

页码：912 / 915

页数：4

共 13 条

[1] SUSPENSION, EMULSION, AND DISPERSION POLYMERIZATION - A METHODOLOGICAL SURVEY [J].

ARSHADY, R .

COLLOID AND POLYMER SCIENCE, 1992, 270 (08) :717-732

[2]

Brandup J., 1989, POLYM HDB

[3] HOMOGENEOUS FREE-RADICAL POLYMERIZATIONS IN CARBON-DIOXIDE .3. TELOMERIZATION OF 1,1-DIFLUOROETHYLENE IN SUPERCRITICAL CARBON-DIOXIDE [J].

COMBES, JR ;

GUAN, Z ;

DESIMONE, JM .

MACROMOLECULES, 1994, 27 (03) :865-867

[4] SYNTHESIS OF FLUOROPOLYMERS IN SUPERCRITICAL CARBON-DIOXIDE [J].

DESIMONE, JM ;

GUAN, Z ;

ELSBERND, CS .

SCIENCE, 1992, 257 (5072) :945-947

[5]

DESIMONE JM, 1994, SCIENCE, V256, P356

[6]

FUKUI K, 1970, Patent No. 3522223

[7] HOMOGENEOUS FREE-RADICAL POLYMERIZATIONS IN SUPERCRITICAL CARBON-DIOXIDE .2. THERMAL-DECOMPOSITION OF 2,2'-AZOBIS(ISOBUTYRONITRILE) [J].

GUAN, ZB ;

COMBES, JR ;

MENCELOGLU, YZ ;

DESIMONE, JM .

MACROMOLECULES, 1993, 26 (11) :2663-2669

[8]

HARTMANN H, 1989, Patent No. 4748220

[9]

HUVARD GS, 1988, Patent No. 881121982

[10]

McHugh M.A., 1994, SUPERCRITICAL FLUID, Vsecond

← 1 2 →