TEMPLATE SYNTHESIS OF SUBSTITUTED CYCLOPENTANONES BY ZIRCONOCENE/OLEFIN/CO SYSTEMS

被引：32

作者：

AKITA, M ^{[1
]}

YASUDA, H ^{[1
]}

YAMAMOTO, H ^{[1
]}

NAKAMURA, A ^{[1
]}

机构：

[1] OSAKA UNIV,FAC SCI,DEPT MACROMOLEC SCI,TOYONAKA,OSAKA 560,JAPAN

来源：

POLYHEDRON | 1991年 / 10卷 / 01期

关键词：

D O I：

10.1016/S0277-5387(00)83539-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of 3,4-dialkylcyclopentanones was synthesized by template reactions on the "Cp2Zr" moiety generated from Cp2Zr(2,4-hexadiene) or Cp2Zr(olefin) complexes by ligand exchange reactions. The addition of a 1-olefin or 1,7-octadiene to the Cp2Zr species followed by CO insertion and acid hydrolysis gave a cis- or trans-disubstituted cyclopentanone in high yield.

引用

页码：1 / 9

页数：9

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