ASYMMETRIC TRANSFER HYDROGENATION OF PROCHIRAL CARBOXYLIC-ACIDS CATALYZED BY A 5-COORDINATE RU(II)-BINAP COMPLEX

被引：46

作者：

SABURI, M

OHNUKI, M

OGASAWARA, M

TAKAHASHI, T

UCHIDA, Y

机构：

[1] Department of Industrial Chemistry, Faculty of Engineering, The University of Tokyo, Hongo, Bunkyo-Ku, Tokyo

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 39期

关键词：

ASYMMETRIC TRANSFER HYDROGENATION; RU-BINAP CATALYST; RU-HYDRIDE COMPLEX; ALCOHOLS; CHIRAL CARBOXYLIC ACIDS;

D O I：

10.1016/0040-4039(92)89031-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Asymmetric transfer bydrogenation of representative prochiral carboxylic acids was performed, using [RuH((S)-binap)2]PF6 or a related complex as a catalyst and 2-propanol or ethanol as a hydrogen source, to achieve good to excellent enantioselectivities.

引用

页码：5783 / 5786

页数：4

共 16 条

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