PREPARATION AND PROPERTIES OF ALKYLPALLADIUM(II) AND ALKYLPLATINUM(II) ALKYNYL COMPLEXES

被引：13

作者：

KIM, YJ ^{[1
]}

OSAKADA, K ^{[1
]}

YAMAMOTO, A ^{[1
]}

机构：

[1] TOKYO INST TECHNOL,RESOURCES UTILIZAT RES LAB,4259 NAGATSUTA,MIDORI KU,YOKOHAMA,KANAGAWA 227,JAPAN

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 452卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(93)83198-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of methylpalladium alkoxide complex, PdMe(OCH(CF3)2)(dppe) (dppe = 1,2-bis(diphenylphosphino)ethane) with phenylacetylene gives PdMe(C=CPh)(dppe) (I). Methylpalladium and -platinum alkoxide complexes having PMe3 ligands also react with phenylacetylene to give trans-PdMe(C-CPh)(PMe3)2 (II) and trans-PtMe(C=CPh)(PMe3)2 (III), respectively. The complexes were characterized by IR and NMR spectroscopy as well as by elemental analyses. Thermolysis of complexes I-III causes reductive elimination of MeC=CPh in 97-98% yields. Reaction of I with CO at 1 atm gives MeC=CPh while the reaction with CO at 10 atm gives a mixture of MeCOC=CPh and MeC=CPh. Complex III does not react with CO at 1 atm.

引用

收藏

页码：247 / 250

页数：4

相关论文

共 36 条

[1] REACTION OF CATIONIC DIIRON MU-ETA-1-ETA-2-ACETYLIDE COMPLEXES [(FP)2(C=CR)]BF4 (R = H, PH) WITH CARBON NUCLEOPHILES AND HYDRIDE - FORMATION OF MU-VINYLIDENE COMPLEXES [J].

AKITA, M ;

TERADA, M ;

MOROOKA, Y .

ORGANOMETALLICS, 1991, 10 (08) :2961-2965

[2] REACTION OF THE CATIONIC DIIRON MU-ETA-1-ETA-2-ACETYLIDE COMPLEXES [(FP)2(C=CR)]BF4 (R = H, PH) WITH NAOME [J].

AKITA, M ;

TERADA, M ;

OYAMA, S ;

SUGIMOTO, S ;

MOROOKA, Y .

ORGANOMETALLICS, 1991, 10 (05) :1561-1568

[3] KINETIC AND MECHANISTIC INVESTIGATION OF THE SEQUENTIAL HYDROGENATION OF PHENYLACETYLENE CATALYZED BY OSHCL(CO) (PME-TERT-BU2)2, OSHCL(CO)(P-I-PR3)2 [J].

ANDRIOLLO, A ;

ESTERUELAS, MA ;

MEYER, U ;

ORO, LA ;

SANCHEZDELGADO, RA ;

SOLA, E ;

VALERO, C ;

WERNER, H .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (19) :7431-7437

[4] RELATIVE METAL HYDROGEN, METAL OXYGEN, METAL NITROGEN, AND METAL-CARBON BOND STRENGTHS FOR ORGANORUTHENIUM AND ORGANOPLATINUM COMPOUNDS - EQUILIBRIUM STUDIES OF CPSTAR(PME3)2RUX AND (DPPE)MEPTX SYSTEMS [J].

BRYNDZA, HE ;

FONG, LK ;

PACIELLO, RA ;

TAM, W ;

BERCAW, JE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (05) :1444-1456

[5] MECHANISM OF OLEFIN INSERTION INTO METAL OXYGEN BONDS - REACTION OF [(C6H5)2PCH2CH2P(C6H5)2]PT(CH3)(OCH3) WITH TETRAFLUOROETHYLENE [J].

BRYNDZA, HE .

ORGANOMETALLICS, 1985, 4 (02) :406-408

[6] REACTION OF (DPPE)PT(CH3)(OCH3) WITH TETRAFLUOROETHYLENE - SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF (DPPE)PT(CH3)(CF2CF2OCH3) [J].

BRYNDZA, HE ;

CALABRESE, JC ;

WREFORD, SS .

ORGANOMETALLICS, 1984, 3 (10) :1603-1604

[7]

CARDIN CJ, 1978, J CHEM SOC DALTON, P46, DOI 10.1039/dt9780000046

[8] CHEMISTRY OF METAL-HYDRIDES .27. KINETIC AND ELECTRON-SPIN-RESONANCE STUDIES OF ACETYLENE INSERTION REACTIONS WITH PLATINUM(II) DIHYDRIDES AND THE CRYSTAL-STRUCTURE DETERMINATION OF TRANS-PTH(P-TRANS-BU2-NORMAL-BU)2(CH3OOCC=CHCOOCH3) [J].

CLARK, HC ;

FERGUSON, G ;

GOEL, AB ;

JANZEN, EG ;

RUEGGER, H ;

SIEW, PY ;

WONG, CS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (22) :6961-6972

[9]

COLLMAN JP, 1987, PRINCIPLES APPLICATI

[10] SYNTHESES, REACTIONS, AND MOLECULAR-STRUCTURES OF TRANS-HYDRIDO(PHENYLAMIDO)BIS(TRIETHYLPHOSPHINE)PLATINUM(II) AND TRANS-HYDRIDOPHENOXOBIS(TRIETHYLPHOSPHINE)PLATINUM(II) [J].

COWAN, RL ;

TROGLER, WC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (13) :4750-4761

← 1 2 3 4 →