MULTIPOLAR FRAMEWORK CHEMISTRY - GALLIUM-CONTAINING AND PHOSPHORUS-CONTAINING HETEROCYCLES

被引：3

作者：

WEBB, KM ^{[1
]}

MILLER, NE ^{[1
]}

机构：

[1] UNIV S DAKOTA,DEPT CHEM,VERMILLION,SD 57069

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 460卷 / 01期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0022-328X(93)80350-K

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel six-membered heterocycle with B, Ga, N, and P heteroatoms, Me2GaCH2PMe2BH2CH2NMe2, is synthesized from a lithiated borane base. Its reaction with anhydrous acids leads to Ga-Me bond cleavage and formation of monosubstituted derivatives. A similar derivative chemistry pertains for the analogous heterocycle, Me2GaCH2NMe2BH2CH2NMe2. Two related six-membered heterocycles with phosphonia atoms are also characterized, one with a thionia ring atom and one a spiroheterocycle with piperidine: Me2P(CH2BH2)2SMe and Me2P(CH2BH2)2N(CH2)2CH2.

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页码：1 / 6

页数：6

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