IDENTIFICATION AND QUANTIFICATION OF INORGANIC AND ORGANIC SELENIUM-COMPOUNDS WITH HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHY

被引:74
作者
KOLBL, G
KALCHER, K
IRGOLIC, KJ
MAGEE, RJ
机构
[1] GRAZ UNIV, INST ANALYT CHEM, UNIV PL 1, A-8010 GRAZ, AUSTRIA
[2] LA TROBE UNIV, DEPT CHEM, BUNDOORA, VIC 3083, AUSTRALIA
关键词
SELENIUM; SELENIUM COMPOUNDS; HIGH-PERFORMANCE LIQUID CHROMATOGRAPHY; SELENIUM-SPECIFIC DETECTORS;
D O I
10.1002/aoc.590070704
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Selenium appears in the natural selenium cycle in the form of several organic and inorganic compounds. The biologically beneficial and detrimental effects of 'selenium' must be ascribed to particular selenium compounds. The identification and quantification of selenium compounds in biological and environmental samples is required for an understanding of the role of selenium. The high-performance liquid-chromatographic (HPLC) methods for the separation, identification and quantification of selenite, selenate, hydrogen selenide, methaneselenol, bis(organothio) selenides, trimethylselenonium salts, selenoamino-acids, selenium derivatives of carbohydrates, selenoproteins, selenonucleosides and other miscellaneous selenium compounds are summarized (193 references) and pertinent detection modes discussed. Advantages and disadvantages of the methods are pointed out. The literature is covered since 1974, the year of the first publication in this field.
引用
收藏
页码:443 / 466
页数:24
相关论文
共 193 条
[1]  
AELVOET C, 1989, ANALUSIS, V17, P131
[2]  
AELVOET C, 1986, ANALUSIS, V14, P523
[3]  
AOYAMA E, 1991, ACS SYM SER, V445, P240
[4]  
AOYAMA E, 1987, BUNSEKI KAGAKU, V36, P801
[5]   DETERMINATION OF SE-75-LABELED SELENITE AND METABOLITES IN PLASMA AND URINE BY HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHY WITH ONLINE RADIOACTIVITY DETECTION [J].
BALDEW, GS ;
DEGOEIJ, JJM ;
VERMEULEN, NPE .
JOURNAL OF CHROMATOGRAPHY-BIOMEDICAL APPLICATIONS, 1989, 496 (01) :111-120
[6]   SELENIUM DESORPTION FROM CA-KAOLINITE [J].
BARYOSEF, B .
COMMUNICATIONS IN SOIL SCIENCE AND PLANT ANALYSIS, 1987, 18 (07) :771-779
[7]   SELENIUM SORPTION BY KAOLINITE AND MONTMORILLONITE [J].
BARYOSEF, B ;
MEEK, D .
SOIL SCIENCE, 1987, 144 (01) :11-19
[9]   SELENOGLUCOSINOLATES IN NATURE - FACT OR MYTH [J].
BERTELSEN, F ;
GISSELNIELSEN, G ;
KJAER, A ;
SKRYDSTRUP, T .
PHYTOCHEMISTRY, 1988, 27 (12) :3743-3749
[10]  
Bjerg B, 1987, GLUCOSINOLATES RAPES, P125