ALPHA-REGIOSELECTIVE CARBONYL ALLYLATION BY AN ALLYLIC TIN COMPOUND PREPARED FROM 1-BROMOBUT-2-ENE AND TIN(II) BROMIDE AT A NONPOLAR ORGANIC-AQUEOUS INTERFACE

被引：15

作者：

MASUYAMA, Y

KISHIDA, M

KURUSU, Y

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 14期

关键词：

D O I：

10.1039/c39950001405

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

1-Bromobut-2-ene on a dichloromethane-water biphasic system at 25 degrees C causes alpha-regioselective addition to aldehydes with SnBr2 to produce 1-substituted pent-3-en-1-ols, and causes gamma-regioselective addition to aldehydes with SnBr2-Bu(4)NBr to produce 1-substituted 2-methylbut-3-en-1-ols.

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页码：1405 / 1406

页数：2

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