KINETIC COMPENSATION EFFECT AS A MATHEMATICAL CONSEQUENCE OF THE EXPONENTIAL RATE-CONSTANT

被引：124

作者：

KOGA, N ^{[1
]}

SESTAK, J ^{[1
]}

机构：

[1] HIROSHIMA UNIV,FAC SCH EDUC,CHEM LAB,MINAMI KU,HIROSHIMA 734,JAPAN

来源：

THERMOCHIMICA ACTA | 1991年 / 182卷 / 02期

关键词：

D O I：

10.1016/0040-6031(91)80005-4

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

It is shown that the kinetic compensation effect mathematically results from the exponential form of the rate constant. A change of activation energy is thus compensated by the same change in temperature or in the logarithm of the pre-exponential factor.

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页码：201 / 208

页数：8

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