SYNTHESIS OF NONRACEMIC 2-VINYL-MONOPROTECTED 1,3-DIOLS FROM THE REACTIONS OF CHIRAL ALLYLSTANNANES WITH ALDEHYDES

被引：4

作者：

GUNG, BW

PEAT, AJ

机构：

[1] Department of Chemistry, Miami University, Oxford

来源：

SYNTHETIC COMMUNICATIONS | 1991年 / 21卷 / 17期

关键词：

D O I：

10.1080/00397919108021579

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new approach for the synthesis of 2-vinyl monoprotected 1,3-diols has been developed. By employing different Lewis acid, either anti-anti or anti-syn stereoisomer can be selectively prepared.

引用

页码：1797 / 1802

页数：6

共 13 条

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[2] AN ANOMALOUS CASE OF DIASTEREOFACIAL SELECTIVITY IN THE ADDITION OF CHIRAL ALLYLSTANNANES TO BENZALDEHYDE - IS THE INSIDE ALKOXY EFFECT INVOLVED
GUNG, BW
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[3] REMARKABLE INCREASE IN THE DIASTEREOFACIAL SELECTIVITY OF THE ADDITION OF BETA-METHYL ALPHA-(ALKOXY)ALLYLSTANNANE TO ALDEHYDES - SUBSTITUENT EFFECTS ON DIASTEREOFACIAL SELECTIVITY
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[7] DIASTEREOSELECTIVE ADDITIONS OF ENANTIOENRICHED (GAMMA-ALKOXYALLYL)STANNANES TO ALPHA-ALKOXY ALDEHYDES - A SYNTHETIC ROUTE TO CARBOHYDRATES
MARSHALL, JA
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[J]. JOURNAL OF ORGANIC CHEMISTRY, 1991, 56 (02) : 483 - 485
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MARSHALL, JA
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[9] SYNTHESIS OF HOMOCHIRAL ALPHA-ALKOXYSTANNANES - STEREOSPECIFIC CONVERSION TO CEMBRANOLIDE PRECURSORS
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[J]. TETRAHEDRON LETTERS, 1988, 29 (14) : 1657 - 1660
[10] STILL WC, MACROMODEL 2 5

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