HYDROGENATION OF ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS BY CARBON-MONOXIDE AND WATER WITH RH6(CO)16 CATALYST UNDER MILD CONDITIONS

被引：7

作者：

JOH, T

FUJIWARA, K

TAKAHASHI, S

机构：

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1993年 / 66卷 / 03期

关键词：

D O I：

10.1246/bcsj.66.978

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

By controlling such factors as the concentration of water and amine, the carbon-carbon double bond of alpha,beta-unsaturated carbonyl compounds could be selectively hydrogenated under mild water-gas shift reaction (WGSR) conditions using a Rh6(CO)16-Et3N catalyst system. The reaction proceeded at room temperature under atmospheric pressure of CO.

引用

收藏

页码：978 / 980

页数：3

相关论文

共 7 条

[1] CHEMISTRY OF METAL CARBONYLS .54. SYNTHESIS OF RHODIUM AND IRIDIUM CARBONYLS [J].

CHASTON, SHH ;

STONE, FGA .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1969, (03) :500-&

[2] APPLICATIONS OF THE WATER GAS SHIFT REACTION - USE OF THE CO/H2O COUPLE FOR THE CONVERSION OF VARIOUS ORGANIC SUBSTRATES CATALYZED BY TRANSITION-METAL COMPLEXES [J].

ESCAFFRE, P ;

THOREZ, A ;

KALCK, P .

JOURNAL OF MOLECULAR CATALYSIS, 1985, 33 (01) :87-118

[3] NUCLEOPHILIC ACTIVATION OF CARBON-MONOXIDE - APPLICATIONS TO HOMOGENEOUS CATALYSIS BY METAL-CARBONYLS OF THE WATER GAS SHIFT AND RELATED REACTIONS [J].

FORD, PC ;

ROKICKI, A .

ADVANCES IN ORGANOMETALLIC CHEMISTRY, 1988, 28 :139-217

[4] COBALT-CATALYZED CYCLOCARBONYLATION OF ACETYLENES UNDER WATER GAS SHIFT CONDITIONS - SELECTIVE SYNTHESIS OF INDAN-1-ONES [J].

JOH, T ;

DOYAMA, K ;

FUJIWARA, K ;

MAESHIMA, K ;

TAKAHASHI, S .

ORGANOMETALLICS, 1991, 10 (02) :508-513

[5] RHODIUM-CATALYZED CARBONYLATION OF ACETYLENES UNDER WATER-GAS SHIFT REACTION CONDITIONS - SELECTIVE SYNTHESIS OF FURAN-2(5H)-ONES [J].

JOH, T ;

DOYAMA, K ;

ONITSUKA, K ;

SHIOHARA, T ;

TAKAHASHI, S .

ORGANOMETALLICS, 1991, 10 (07) :2493-2498

[6] SELECTIVE HYDROGENATION OF ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS AND NITRILES CATALYZED BY POLYMER-SUPPORTED RHODIUM CARBONYL-COMPLEXES [J].

KITAMURA, T ;

JOH, T .

NIPPON KAGAKU KAISHI, 1985, (03) :473-478

[7]

LAINE R, 1988, J MOL CATAL, V44, P87