ULTRASONIC DESTRUCTION OF CHLORINATED COMPOUNDS IN AQUEOUS-SOLUTION

被引:80
作者
WU, JM
HUANG, HS
LIVENGOOD, CD
机构
[1] Energy Systems Division, Argonne National Laboratory, Argonne, Illinois
来源
ENVIRONMENTAL PROGRESS | 1992年 / 11卷 / 03期
关键词
D O I
10.1002/ep.670110313
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The application of ultrasonic-wave energy for the destruction of low concentrations of carbon tetrachloride into nonhazardous end products is described, and the results of experimental work are presented. Process parameters studied included steady-state temperature, concentration, pH, irradiation time, and the intensity of the applied ultrasonic-wave energy. Greater than 99% destruction efficiencies were achieved through this process, and the irradiation time required for a given degree of destruction decreased with increasing intensity of the ultrasonic energy. In addition, a detailed chemical reaction mechanism for the destruction of carbon tetrachloride in water was formulated. The agreement between the model and experimental results is generally good.
引用
收藏
页码:195 / 201
页数:7
相关论文
共 22 条
[1]  
Richards W.T., Loomis A.L., J. Am. Chem. Soc., 49, (1927)
[2]  
Suslick K.S., Science, 247, (1990)
[3]  
Mason T.J., Lorimer J.P., Sonochemistry: Theory, Applications and Uses of Ultrasound in Chemistry, (1988)
[4]  
Weissler A., Cooper H.W., Snyder S., J. Am. Chem. Soc., 72, (1950)
[5]  
Agranonik Ya.R., Karpukhin V.F., Fayngold Z.L., Antibiotiki i Khimioterapiya, Russ., 35, pp. 48-51, (1986)
[6]  
Cheung H.M., Bhatnagar A., Jansen G., Environmental Science & Technology, 25, 8, (1991)
[7]  
Mason T.J., Chemistry with Ultrasound, (1990)
[8]  
Suslick K.S., Hammerton D.A., Cline D.E., J. Am. Chem. Soc., 108, (1986)
[9]  
Shutilov V.A., Fundamental Physics of Ultrasound, (1988)
[10]  
Kotronarou A., Mills G., Hoffmann M.R., J. Phys. Chem., 95, pp. 3630-3638, (1991)