AN APPROACH TO THE SOLUTION OF THE INVERSE KINETIC PROBLEM IN THE CASE OF COMPLEX PROCESSES .1. METHODS EMPLOYING A SERIES OF THERMOANALYTICAL CURVES

被引:237
作者
VYAZOVKIN, SV
LESNIKOVICH, AI
机构
[1] Institute of Physico-Chemical Problems, Byelorussian State University
关键词
D O I
10.1016/0040-6031(90)80227-P
中图分类号
O414.1 [热力学];
学科分类号
摘要
An approach to the solution of the inverse kinetic problem in the case of complex processes is proposed. This approach is based on the analysis of the dependence of activation energy calculated by the isoconversion method on the transformation degree. The inter-relationship between the shape of this dependence and the type of process has been determined. An algorithm for identifying the type of complex process in the simplest case is proposed. The possibility of assessing the parameters of individual stages has been investigated. All the calculations have been made using the isoconversion method for several model thermoanalytical curves. © 1990.
引用
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页码:273 / 280
页数:8
相关论文
共 22 条
[1]   THE THERMAL-DECOMPOSITION OF OXALATES - A REVIEW [J].
DOLLIMORE, D .
THERMOCHIMICA ACTA, 1987, 117 :331-363
[2]   A COMPUTER-PROGRAM SYSTEM FOR KINETIC-ANALYSIS OF NON-ISOTHERMAL THERMOGRAVIMETRIC DATA .2. GENERALIZED KINETIC-ANALYSIS AND APPLICATION TO COAL PYROLYSIS [J].
ELDER, JP .
THERMOCHIMICA ACTA, 1985, 95 (01) :41-58
[3]   THE ISOCONVERSIONAL METHOD FOR DETERMINATION OF ENERGY OF ACTIVATION AT CONSTANT HEATING RATES - CORRECTIONS FOR THE DOYLE APPROXIMATION [J].
FLYNN, JH .
JOURNAL OF THERMAL ANALYSIS, 1983, 27 (01) :95-102
[4]  
GONTKOVSKAYA VT, 1988, KHIM FIZ, V7, P214
[5]   A METHOD OF FINDING INVARIANT VALUES OF KINETIC-PARAMETERS [J].
LESNIKOVICH, AI ;
LEVCHIK, SV .
JOURNAL OF THERMAL ANALYSIS, 1983, 27 (01) :89-94
[6]  
LESNIKOVICH AI, 1985, J THERM ANAL, V30, P667
[7]  
Logvinenko, 1982, THERMAL ANAL COORDIN
[8]   KINETIC-STUDY OF THE THERMAL DEHYDRATION OF CALCIUM-OXALATE MONOHYDRATE [J].
MASUDA, Y ;
ITO, Y ;
ITO, R ;
IWATA, K .
THERMOCHIMICA ACTA, 1986, 99 :205-215
[9]   A NEW METHOD OF ANALYZING THERMOGRAVIMETRIC DATA [J].
OZAWA, T .
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1965, 38 (11) :1881-+
[10]   DETERMINATION OF ACTIVATION ENERGIES OF CHEMICAL REACTIONS BY DIFFERENTIAL THERMAL ANALYSIS [J].
PILOYAN, GO ;
RYABCHIK.ID ;
NOVIKOVA, OS .
NATURE, 1966, 212 (5067) :1229-&